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008 131105s2014 nju ob 001 0 eng
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019 _a908035553
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020 _a9781118711569 (epub)
020 _a1118711564 (epub)
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020 _a111871170X (pdf)
020 _a9781118711620 (mobi)
020 _a1118711629 (mobi)
020 _z9781118207949 (cloth)
020 _a9781118711613
020 _a1118711610
020 _a1118207947
020 _a9781118207949
020 _a9781306638869
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035 _a(OCoLC)862222401
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042 _apcc
050 0 0 _aQD505
072 7 _aSCI
_x013040
_2bisacsh
082 0 0 _a547/.215
_223
049 _aMAIN
245 0 0 _aOlefin metathesis :
_btheory and practice /
_cedited by Dr. Karol Grela, Institute of Organic Chemistry, Kasprzaka, Poland.
264 1 _aHoboken, New Jersey :
_bWiley,
_c[2014]
300 _a1 online resource.
336 _atext
_2rdacontent
337 _acomputer
_2rdamedia
338 _aonline resource
_2rdacarrier
500 _a"Zespol III."
504 _aIncludes bibliographical references and index.
588 _aDescription based on print version record and CIP data provided by publisher.
520 _aThis is a complete examination of the theory and methods of modern olefin metathesis, one of the most widely used chemical reactions in research and industry. Provides basic information for non-specialists, while also explaining the latest trends and advancements in the field to experts. Discusses the various types of metathesis reactions, including CM, RCM, enyne metathesis, ROMP, and tandem processes, as well as their common applications. Outlines the tools of the trade-from the important classes of active metal complexes to optimal reaction conditions.
505 0 _aTitle Page; Copyright; Preface; Reference; Contributors; Part I: Applications of Olefin Metathesis Reactions; Section 1: Introduction; Chapter 1: Olefin Metathesis Reactions: From A Historical Account to Recent Trends; 1.1 Introduction; 1.2 The Metathesis Reactions: Exchanges of Carbenes and Carbynes; 1.3 The Early Days of Olefin Metathesis in American Industry; 1.4 Unsuccessful Attempts to Solve the Mechanistic Puzzle; 1.5 The Chauvin Mechanism: A Metathesis Dance; 1.6 The Importance of the Chauvin Mechanism for Overall Organometallic Catalysis
505 8 _a1.7 Schrock's High Oxidation State Alkylidene and Alkylidyne Complexes1.8 Grubbs' Approach and the Ru Olefin Metathesis Catalysts; 1.9 Olefin Metathesis in Aqueous Solvents and Water; 1.10 Olefin Metathesis in Other "Green Solvents": Ionic Liquids and CO2; 1.11 Solid Catalyst Supports; 1.12 Metal Contamination of the Metathesis Reaction Products; 1.13 Industrial Applications; 1.14 Applications to Organic Synthesis; 1.15 Alkyne Metathesis; 1.16 Alkane Metathesis; 1.17 Polymerization Metathesis and Polymer Materials; 1.18 Concluding Remarks; Acknowledgments; References
505 8 _aSection 2: Types of Olefin Metathesis ReactionsChapter 2: Cross Metathesis; 2.1 Introduction; 2.2 Functional Group Influence on the Metathesis Outcome; 2.3 E/Z Selectivity Control; 2.4 Outlook and Perspectives; Acknowledgments; References; Chapter 3: Ring-Closing Metathesis; 3.1 Introduction; 3.2 General Factors in Cyclization Efficiency; 3.3 Scope, Challenges, and Opportunities; 3.4 Practical Aspects; 3.5 Practical Examples; 3.6 Industrial Applications of RCM; 3.7 Conclusions; Acknowledgments; References; Chapter 4: Ene-Yne Metathesis; 4.1 Introduction
505 8 _a4.2 Ene-Yne Metathesis not Involving Cascades4.3 Tandem Processes Involving En(e)Yne Metathesis; 4.4 Conclusion and Outlook; References; Chapter 5: Domino and other Olefin Metathesis Reaction Sequences; 5.1 Introduction; 5.2 Domino Reactions; 5.3 Metathesis/Non-Metathesis Reaction Sequences; References; Chapter 6: Enantioselective Olefin Metathesis; 6.1 General Introduction; 6.2 Asymmetric Ring-Closing Metathesis (ARCM); 6.3 Tandem Asymmetric Ring-Opening/Cross Metathesis (AROM/CM) or Tandem Asymmetric Ring-Opening/Cross-Closing Metathesis (AROM/RCM); 6.4 Conclusion; References
505 8 _aChapter 7: Olefin Metathesis Polymerization7.1 Introduction; 7.2 ROMP-The Mechanism; 7.3 The Initiators/Catalysts; 7.4 ROMP-The Monomers; 7.5 ROMP-Applications; 7.6 Acyclic Diene Metathesis; 7.7 Cyclopolymerizations; 7.8 Conclusions; References; Section 3: Applications of Olefin Metathesis Reactions; Chapter 8: Applications in the Synthesis of Natural and Biologically Active Molecules; 8.1 Introduction; 8.2 Ring-Closing Metathesis (RCM); 8.3 Relay Ring-Closing Metathesis (RRCM); 8.4 Temporary Tether and RCM (TT-RCM); 8.5 Cross-Metathesis (CM); 8.6 Ring-Opening Metathesis (ROM)
650 0 _aMetathesis (Chemistry)
650 0 _aCatalysis.
650 0 _aAlkenes.
650 7 _aSCIENCE
_xChemistry
_xOrganic.
_2bisacsh
650 7 _aAlkenes.
_2fast
_0(OCoLC)fst00805415
650 7 _aCatalysis.
_2fast
_0(OCoLC)fst00848867
650 7 _aMetathesis (Chemistry)
_2fast
_0(OCoLC)fst01018340
655 4 _aElectronic books.
655 0 _aElectronic books.
700 1 _aGrela, Karol,
_d1970-
_eeditor of compilation.
776 0 8 _iPrint version:
_tOlefin metathesis
_dHoboken, New Jersey : John Wiley & Sons, [2014]
_z9781118207949
_w(DLC) 2013041990
856 4 0 _uhttp://onlinelibrary.wiley.com/book/10.1002/9781118711613
_zWiley Online Library
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