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008 130314s2013 nju ob 001 0 eng
010 _a 2013010397
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019 _a857437591
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020 _a9781118629994 (epub)
020 _a111862999X (epub)
020 _a9781118630167 (pdf)
020 _a1118630165 (pdf)
020 _a9781118630181 ( mobi)
020 _a1118630181 ( mobi)
020 _z9781118148921 (hardback)
020 _a9781118629871
020 _a1118629876
020 _a9781299731738 (MyiLibrary)
020 _a1299731732 (MyiLibrary)
020 _z1118148924 (hbk.)
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049 _aMAIN
245 0 0 _aTransition-metal-mediated aromatic ring construction /
_cedited by Ken Tanaka, Tokyo University of Agriculture and Technology, Tokyo, Japan.
264 1 _aHoboken, New Jersey :
_bWiley,
_c[2013]
300 _a1 online resource.
336 _atext
_2rdacontent
337 _acomputer
_2rdamedia
338 _aonline resource
_2rdacarrier
520 _a"Recent significant advances with transition-metal-mediated reactions have opened promising new routes to complex aromatic compounds and have been the subject of intense research in recent years. Featuring practical and efficient reactions to help organic chemists synthesize an important class of compounds, Transition-Metal-Mediated Aromatic Ring Construction provides a valuable guide to methods, synthetic routes, and strategies to construct aromatic rings. Chapters devoted to efficient and practical reactions demonstrate how to use them for the synthesis of various complex aromatic compounds"--
_cProvided by publisher.
520 _a"This book covers transition-metal-mediated reactions with applications for constructing aromatic rings, which are an important class of industrial chemical compounds"--
_cProvided by publisher.
504 _aIncludes bibliographical references and index.
588 _aDescription based on print version record and CIP data provided by publisher.
505 0 _aTitle Page; Copyright; Contributors; Preface; Part I: [2 + 2 + 2] and Related Cycloaddition Reactions; Chapter 1: Cobalt-Mediated [2 + 2 + 2] Cycloaddition; 1.1 INTRODUCTION; 1.2 SYNTHESIS OF BENZENES; 1.3 SYNTHESIS OF HETEROCYCLES; 1.4 MECHANISTIC ASPECTS; 1.5 SYNTHETIC APPLICATIONS; 1.6 SUMMARY AND OUTLOOK; REFERENCES; Chapter 2: Nickel-Mediated [2 + 2 + 2] Cycloaddition; 2.1 INTRODUCTION; 2.2 SYNTHESIS OF BENZENES; 2.3 CYCLOADDITION OF ALKYNES AND NITRILES; 2.4 CYCLOADDITION OF ALKYNES AND IMINES; 2.5 CYCLOADDITION OF ALKYNES AND CARBON DIOXIDE; 2.6 CYCLOADDITION OF ALKYNES AND ISOCYANATES
505 8 _a2.7 CYCLOADDITION OF ALKYNES AND CARBODIIMIDE2.8 CYCLOADDITION OF DIYNES AND KETENES; 2.9 CYCLOADDITION OF ARYNES; 2.10 MECHANISM; 2.11 SUMMARY AND OUTLOOK; REFERENCES; Chapter 3: Ruthenium-Mediated [2 + 2 + 2] Cycloaddition; 3.1 INTRODUCTION; 3.2 SYNTHESIS OF BENZENES; 3.3 SYNTHESIS OF HETEROCYCLES; 3.4 MECHANISM OF RUTHENIUM-CATALYZED [2 + 2 + 2] CYCLOADDITIONS; 3.5 SYNTHETIC APPLICATIONS; 3.6 SUMMARY AND OUTLOOK; REFERENCES; Chapter 4: Rhodium-Mediated [2 + 2 + 2] Cycloaddition; 4.1 INTRODUCTION; 4.2 SYNTHESIS OF BENZENES; 4.3 SYNTHESIS OF PYRIDINES
505 8 _a4.4 SYNTHESIS OF PYRIDONES AND RELATED HETEROCYCLES4.5 SUMMARY AND OUTLOOK; REFERENCES; Chapter 5: Iridium-Mediated [2 + 2 + 2] Cycloaddition; 5.1 INTRODUCTION; 5.2 SYNTHESIS OF BENZENE DERIVATIVES; 5.3 SYNTHESIS OF HETEROCYCLIC COMPOUNDS; 5.4 MECHANISTIC ASPECTS; 5.5 SUMMARY AND OUTLOOK; REFERENCES; Chapter 6: [2 + 2 + 2] and Related Cycloadditions Mediated by Other Transition Metals; 6.1 INTRODUCTION; 6.2 PALLADIUM-CATALYZED [2 + 2 + 2] AND [2 + 2 + 1] CYCLOADDITIONS; 6.3 IRON-CATALYZED [2 + 2 + 2] CYCLOADDITION; 6.4 MANGANESE-CATALYZED [2 + 2 + 2] CYCLOADDITION
505 8 _a6.5 RHENIUM-CATALYZED [2 + 2 + 2], [2 + 1 + 2 + 1], AND [2 + 2 + 1 + 1] CYCLOADDITIONS6.6 OTHER TRANSITION-METAL-CATALYZED [2 + 2 + 2] CYCLOADDITION; 6.7 SUMMARY AND OUTLOOK; REFERENCES; Chapter 7: Application to the Synthesis of Natural Products; 7.1 INTRODUCTION; 7.2 CONSTRUCTION OF BENZENE RINGS; 7.3 CONSTRUCTION OF A HETEROCYCLIC RING; 7.4 MISCELLANEOUS; 7.5 SUMMARY AND OUTLOOK; REFERENCES; Chapter 8: Synthesis of Planar Chiral Aromatic Compounds via [2 + 2 + 2] Cycloaddition; 8.1 INTRODUCTION; 8.2 COBALT-CATALYZED [2 + 2 + 2] CYCLOADDITION; 8.3 RHODIUM-CATALYZED [2 + 2 + 2] CYCLOADDITION
505 8 _a8.4 ENANTIOSELECTIVE [2 + 2 + 2] CYCLOADDITION8.5 SUMMARY AND OUTLOOK; REFERENCES; Chapter 9: Synthesis of Axially Chiral Aromatic Compounds via [2 + 2 + 2] Cycloaddition; 9.1 INTRODUCTION; 9.2 COBALT-CATALYZED ENANTIOSELECTIVE [2 + 2 + 2] CYCLOADDITION; 9.3 IRIDIUM-CATALYZED ENANTIOSELECTIVE [2 + 2 + 2] CYCLOADDITION; 9.4 RHODIUM-CATALYZED ENANTIOSELECTIVE [2 + 2 + 2] CYCLOADDITION; 9.5 ENANTIOSELECTIVE SYNTHESIS OF AXIALLY CHIRAL ANILIDES AND BEZAMIDES; 9.6 SUMMARY AND OUTLOOK; REFERENCES; Chapter 10: Synthesis of Helically Chiral Aromatic Compounds via [2 + 2 + 2] Cycloaddition
650 0 _aAromatic compounds
_xSynthesis.
650 0 _aTransition metal catalysts.
650 7 _aSCIENCE / Chemistry / Organic.
_2bisacsh
650 7 _aAromatic compounds
_xSynthesis.
_2fast
_0(OCoLC)fst00815028
650 7 _aTransition metal catalysts.
_2fast
_0(OCoLC)fst01154758
655 4 _aElectronic books.
655 0 _aElectronic books.
655 7 _aElectronic books.
_2local
700 1 _aTanaka, Ken,
_d1967-
776 0 8 _iPrint version:
_tTransition-metal-mediated aromatic ring construction
_dHoboken, New Jersey : Wiley, [2013]
_z9781118148921
_w(DLC) 2012049882
856 4 0 _uhttp://onlinelibrary.wiley.com/book/10.1002/9781118629871
_zWiley Online Library
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