Solvent effects in chemistry / (Record no. 13996)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 06266cam a2200829 i 4500 |
| 001 - CONTROL NUMBER | |
| control field | ocn907133019 |
| 003 - CONTROL NUMBER IDENTIFIER | |
| control field | OCoLC |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20171224114857.0 |
| 006 - FIXED-LENGTH DATA ELEMENTS--ADDITIONAL MATERIAL CHARACTERISTICS--GENERAL INFORMATION | |
| fixed length control field | m o d |
| 007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION | |
| fixed length control field | cr ||||||||||| |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 150409s2015 nju ob 001 0 eng |
| 010 ## - LIBRARY OF CONGRESS CONTROL NUMBER | |
| LC control number | 2015014391 |
| 040 ## - CATALOGING SOURCE | |
| Original cataloging agency | DLC |
| Language of cataloging | eng |
| Description conventions | rda |
| -- | pn |
| Transcribing agency | DLC |
| Modifying agency | N$T |
| -- | IDEBK |
| -- | DG1 |
| -- | RECBK |
| -- | OCLCF |
| -- | YDXCP |
| -- | COO |
| -- | CDX |
| -- | EBLCP |
| -- | OCLCQ |
| -- | DEBBG |
| -- | KSU |
| 019 ## - | |
| -- | 912237441 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 9781119044192 |
| Qualifying information | (pdf) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 1119044197 |
| Qualifying information | (pdf) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 9781119044291 |
| Qualifying information | (epub) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 1119044294 |
| Qualifying information | (epub) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 9781119044307 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 1119044308 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 1119030986 |
| Qualifying information | (cloth) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 9781119030980 |
| Qualifying information | (cloth) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| Cancelled/invalid ISBN | 9781119030980 |
| Qualifying information | (cloth) |
| 029 1# - (OCLC) | |
| OCLC library identifier | GBVCP |
| System control number | 832462586 |
| 029 1# - (OCLC) | |
| OCLC library identifier | DEBBG |
| System control number | BV042989347 |
| 029 1# - (OCLC) | |
| OCLC library identifier | DEBBG |
| System control number | BV043397698 |
| 035 ## - SYSTEM CONTROL NUMBER | |
| System control number | (OCoLC)907133019 |
| Canceled/invalid control number | (OCoLC)912237441 |
| 042 ## - AUTHENTICATION CODE | |
| Authentication code | pcc |
| 050 00 - LIBRARY OF CONGRESS CALL NUMBER | |
| Classification number | QD543 |
| 072 #7 - SUBJECT CATEGORY CODE | |
| Subject category code | SCI |
| Subject category code subdivision | 013050 |
| Source | bisacsh |
| 082 00 - DEWEY DECIMAL CLASSIFICATION NUMBER | |
| Classification number | 541/.34 |
| Edition number | 23 |
| 049 ## - LOCAL HOLDINGS (OCLC) | |
| Holding library | MAIN |
| 100 1# - MAIN ENTRY--PERSONAL NAME | |
| Personal name | Buncel, E. |
| 245 10 - TITLE STATEMENT | |
| Title | Solvent effects in chemistry / |
| Statement of responsibility, etc | Erwin Buncel, Robert A. Stairs. |
| 250 ## - EDITION STATEMENT | |
| Edition statement | Second edition. |
| 264 #1 - | |
| -- | Hoboken, New Jersey : |
| -- | Wiley, |
| -- | [2015] |
| 300 ## - PHYSICAL DESCRIPTION | |
| Extent | 1 online resource. |
| 336 ## - | |
| -- | text |
| -- | txt |
| -- | rdacontent |
| 337 ## - | |
| -- | computer |
| -- | c |
| -- | rdamedia |
| 338 ## - | |
| -- | online resource |
| -- | cr |
| -- | rdacarrier |
| 504 ## - BIBLIOGRAPHY, ETC. NOTE | |
| Bibliography, etc | Includes bibliographical references and index. |
| 588 0# - | |
| -- | Print version record and CIP data provided by publisher. |
| 505 0# - FORMATTED CONTENTS NOTE | |
| Formatted contents note | Title Page; Copyright Page; Contents; Preface to the Second Edition; Preface to the First Edition; Chapter 1 Physicochemical Foundations; 1.1 GENERALITIES; 1.2 CLASSIFICATION OF SOLVENTS; 1.3 SOLVENTS IN THE WORKPLACE AND THE ENVIRONMENT; 1.4 SOME ESSENTIAL THERMODYNAMICS AND KINETICS: TENDENCY AND RATE; 1.5 EQUILIBRIUM CONSIDERATIONS; 1.6 THERMODYNAMIC TRANSFER FUNCTIONS; 1.7 KINETIC CONSIDERATIONS: COLLISION THEORY; 1.8 TRANSITION-STATE THEORY; 1.9 REACTIONS IN SOLUTION; 1.10 DIFFUSION-CONTROLLED REACTIONS; 1.11 REACTION IN SOLUTION AND THE TRANSITION-STATE THEORY; PROBLEMS. |
| 505 8# - FORMATTED CONTENTS NOTE | |
| Formatted contents note | Chapter 2 Unreactive Solvents2.1 INTERMOLECULAR POTENTIALS; 2.2 ACTIVITY AND EQUILIBRIUM IN NONELECTROLYTE SOLUTIONS; 2.3 KINETIC SOLVENT EFFECTS; 2.4 SOLVENT POLARITY; 2.5 ELECTROSTATIC FORCES; 2.6 ELECTROLYTES IN SOLUTION; 2.7 SOLVATION; 2.8 SINGLE ION SOLVATION; 2.9 IONIC ASSOCIATION; 2.10 SOLVENT MIXTURES; 2.11 SALT EFFECTS; PROBLEMS; Chapter 3 Reactive Solvents; 3.1 SPECIFIC SOLUTE/SOLVENT INTERACTIONS; 3.2 HYDROGEN BONDING; 3.3 ACIDS AND BASES IN SOLVENTS; 3.4 BRØNSTED-LOWRY ACIDS AND BASES; 3.5 ACIDITY FUNCTIONS; 3.6 ACIDS AND BASES IN KINETICS; 3.6.1 Mechanisms. |
| 505 8# - FORMATTED CONTENTS NOTE | |
| Formatted contents note | 3.6.2 General Acid-Base Catalysis and Brønsted Relationships3.6.3 Solvent-Effect Studies on the Alpha Effect; 3.6.4 The Kinetic Isotope Effect; 3.7 LEWIS ACIDS AND BASES; 3.8 HARD AND SOFT ACIDS AND BASES (HSAB); 3.9 SCALES OF HARDNESS OR SOFTNESS; 3.10 ACIDS AND BASES IN REACTIVE APROTIC SOLVENTS; 3.11 EXTREMES OF ACIDITY AND BASICITY; 3.12 OXIDATION AND REDUCTION; 3.13 ACIDITY/REDOX DIAGRAMS; 3.14 UNIFICATION OF ACID-BASE AND REDOX CONCEPTS; PROBLEMS; Chapter 4 Chemometrics: Solvent Effects and Statistics; 4.1 LINEAR FREE ENERGY RELATIONSHIPS. |
| 505 8# - FORMATTED CONTENTS NOTE | |
| Formatted contents note | 4.2 CORRELATIONS BETWEEN EMPIRICAL PARAMETERS AND OTHER MEASURABLE SOLVENT PROPERTIES4.3 REPRESENTATION OF CORRELATION DATA ON THE HEMISPHERE; 4.4 SOME PARTICULAR CASES; 4.5 ACIDITY AND BASICITY PARAMETERS; 4.6 BASE SOFTNESS PARAMETERS; 4.7 CONCLUSION; Chapter 5 Theories of Solvent Effects; 5.1 INTRODUCTION: MODELING; 5.2 QUANTUM-MECHANICAL METHODS; 5.2.1 Ab Initio Methods; 5.2.2 Semiempirical Methods; 5.2.3 Density-Functional Theory; 5.3 STATISTICAL-MECHANICAL METHODS; 5.3.1 MC Method; 5.3.2 Molecular Dynamics; 5.4 INTEGRAL EQUATION THEORIES; 5.5 SOLVATION CALCULATIONS; 5.6 SOME RESULTS. |
| 505 8# - FORMATTED CONTENTS NOTE | |
| Formatted contents note | 5.6.1 Microsolvation5.6.2 A Classic Reaction: The SN2 Reaction, Gas-Phase versus Solution; 5.6.3 Solvatochromism: Theoretical Calculations; 5.6.4 Solvation of Organic Molecules; 5.6.5 Bimolecular Reactions: Correcting for Suppressed Translational and Rotational Entropies; 5.6.6 Hydrophobic Solvation; 5.6.7 Solvation of Small Molecules; PROBLEMS; Chapter 6 Dipolar Aprotic Solvents; 6.1 INTRODUCTION; 6.2 ACIDITIES IN DMSO AND THE H-SCALE IN DMSO-H2O MIXTURES; 6.3 USE OF THERMODYNAMIC TRANSFER FUNCTIONS; 6.4 CLASSIFICATION OF RATE PROFILE-MEDIUM EFFECT REACTION TYPES. |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc | This book introduces the concepts, theory and experimental knowledge concerning solvent effects on the rate and equilibrium of chemical reactions of all kinds. It begins with basic thermodynamics and kinetics, building on this foundation to demonstrate how a more detailed understanding of these effects may be used to aid in determination of reaction mechanisms, and to aid in planning syntheses. Consideration is given to theoretical calculations (quantum chemistry, molecular dynamics, etc.), to statistical methods (chemometrics), and to modern day concerns such as ""green"" chemistry, where uti. |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Solvation. |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Chemical reactions. |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Solvents. |
| 650 #4 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Chemical reactions. |
| 650 #4 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Solvation. |
| 650 #4 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Solvents. |
| 650 #7 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | SCIENCE |
| General subdivision | Chemistry |
| -- | Physical & Theoretical. |
| Source of heading or term | bisacsh |
| 650 #7 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Chemical reactions. |
| Source of heading or term | fast |
| -- | (OCoLC)fst00853176 |
| 650 #7 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Solvation. |
| Source of heading or term | fast |
| -- | (OCoLC)fst01125665 |
| 650 #7 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name as entry element | Solvents. |
| Source of heading or term | fast |
| -- | (OCoLC)fst01125677 |
| 655 #4 - INDEX TERM--GENRE/FORM | |
| Genre/form data or focus term | Electronic books. |
| 700 1# - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Stairs, R. A. |
| Fuller form of name | (Robert A.) |
| 776 08 - ADDITIONAL PHYSICAL FORM ENTRY | |
| Display text | Print version: |
| Main entry heading | Buncel, E. |
| Title | Solvent effects in chemistry. |
| Place, publisher, and date of publication | Hoboken, New Jersey : Wiley, [2015] |
| International Standard Book Number | 9781119030980 |
| Record control number | (DLC) 2015010522 |
| 856 40 - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | http://onlinelibrary.wiley.com/book/10.1002/9781119044307 |
| Public note | Wiley Online Library |
| 938 ## - | |
| -- | Coutts Information Services |
| -- | COUT |
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| 938 ## - | |
| -- | EBL - Ebook Library |
| -- | EBLB |
| -- | EBL2075007 |
| 938 ## - | |
| -- | EBSCOhost |
| -- | EBSC |
| -- | 1018533 |
| 938 ## - | |
| -- | Ingram Digital eBook Collection |
| -- | IDEB |
| -- | cis30572242 |
| 938 ## - | |
| -- | Recorded Books, LLC |
| -- | RECE |
| -- | rbeEB00612971 |
| 938 ## - | |
| -- | YBP Library Services |
| -- | YANK |
| -- | 12508640 |
| 938 ## - | |
| -- | YBP Library Services |
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| 938 ## - | |
| -- | YBP Library Services |
| -- | YANK |
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| 994 ## - | |
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| -- | DG1 |
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